SCHOLARLY PUBLICATION

A Series of Highly Stable Mesoporous Metalloporphyrin Fe-MOFs

Kecheng Wang, Dawei Feng, Tian‐Fu Liu, Jie Su, Shuai Yuan, Ying‐Pin Chen, Mathieu Bosch, Xiaodong Zou, Hong-Cai “Joe” Zhou

📖 Journal of the American Chemical Society → 📅 2014-09-23 🔗 DOI: 10.1021/ja507269n

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📄 Abstract

A series of mesoporous metalloporphyrin Fe-MOFs, namely PCN-600(M) (M = Mn, Fe, Co, Ni, Cu), have been synthesized using the preassembled [Fe3O(OOCCH3)6] building block. PCN-600 exhibits a one-dimensional channel as large as 3.1 nm and the highest experimental pore volume of 1.80 cm(3)g(-1) among all the reported porphyrinic MOFs. It also shows very high stability in aqueous solutions with pH values ranging from 2-11 and is to our knowledge the only mesoporous porphyrinic MOF stable under basic aqueous conditions. PCN-600(Fe) has been demonstrated as an effective peroxidase mimic to catalyze the co-oxidation reaction.

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