SCHOLARLY PUBLICATION

A Sodalite-Type Porous Metal−Organic Framework with Polyoxometalate Templates: Adsorption and Decomposition of Dimethyl Methylphosphonate

Feng‐Ji Ma, Shuxia Liu, Chunyan Sun, Dadong Liang, Guojian Ren, Feng Wei, Ya-Guang Chen, Zhong‐Min Su

📖 Journal of the American Chemical Society → 📅 2011-03-03 🔗 DOI: 10.1021/ja109659k

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📄 Abstract

A sodalite-type porous metal-organic framework with polyoxometalate templates, H(3)[(Cu(4)Cl)(3)(BTC)(8)](2)[PW(12)O(40)]·(C(4)H(12)N)(6)·3H(2)O (NENU-11; BTC = 1,3,5-benzenetricarboxylate), was obtained by a hydrothermal reaction. As a reasonable candidate for eliminating nerve gas, NENU-11 displays good adsorption behavior for dimethyl methylphosphonate (15.5 molecules per formula unit). In virtue of the catalytic activity of polyoxometalate guests, this nerve gas mimic could be facilely decomposed by a hydrolysis reaction.

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