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Graphene/Polyaniline Nanocomposite for Hydrogen Sensing

Laith Al-Mashat, Koo Shin, Kourosh Kalantar‐Zadeh, Johan du Plessis, Seung Hoon Han, Robert W. Kojima, Richard B. Kaner, Dan Li, Xinglong Gou, Samuel J. Ippolito, Wojtek Wlodarski

📄 Abstract

Here we report on the synthesis of a graphene/polyaniline (PANI) nanocomposite and its application in the development of a hydrogen (H 2 ) gas sensor. Using a chemical synthetic route, graphene was prepared and ultrasonicated with a mixture of aniline monomer and ammonium persulfate to form PANI on its surface. The developed material was characterized by scanning electron microscopy (SEM), transmission electron microscopy, Raman spectroscopy, and X-ray photoemission spectroscopy. The SEM study revealed that the PANI in the composite has a nanofibrillar morphology. We investigated the H 2 gas sensing performance of this material and compare it with that of the sensors based on only graphene sheets and PANI nanofibers. We found that the graphene/PANI nanocomposite-based device sensitivity is 16.57% toward 1% of H 2 gas, which is much larger than the sensitivities of sensors based on only graphene sheets and PANI nanofibers.

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