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Low‐Cost Hydrogen‐Evolution Catalysts Based on Monolayer Platinum on Tungsten Monocarbide Substrates

Daniel V. Esposito, Sean T. Hunt, Alan Lee Stottlemyer, Kevin D. Dobson, Brian E. McCandless, Robert W. Birkmire, Jingguang G. Chen

📄 Abstract

How low can you go? The lower limits of platinum loading, in the sub-monolayer to monolayer range, have been explored for the hydrogen evolution reaction (HER). A low-cost substrate material, tungsten monocarbide (see picture; W blue, C small gray spheres) is capable of supporting monolayer amounts of platinum (large blue-gray spheres) to produce an electrocatalyst with the same HER activity as bulk platinum.

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