Origins of the p -type nature and cation deficiency in Cu2O and related materials

While most of crystalline wide gap oxides are both stoichiometric and insulating, a handful of them including ZnO and ${mathrm{In}}_{2}{mathrm{O}}_{3}$ are naturally anion-deficient and electron conductors. Even fewer of the oxides are naturally cation-deficient and hole conductors, the arch-type of which is ${mathrm{Cu}}_{2}mathrm{O}$. Based on first principles calculation of equilibrium nonstoichiometry and defect stability, we explain why the ${mathrm{Cu}}^{(I)}({d}^{10})$ oxide-based materials are both $p$-type and naturally cation-deficient, and why cation vacancies lead to delocalized, conductive states, whereas in other oxides (e.g., ZnO and MgO), they lead to localized, nonconductive states.