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Reduced voltage losses yield 10% efficient fullerene free organic solar cells with >1 V open circuit voltages

Derya Baran, Thomas Kirchartz, Scot Wheeler, Stoichko D. Dimitrov, Maged Abdelsamie, Jeffrey A. Gorman, Raja Shahid Ashraf, Sarah Holliday, Andrew Wadsworth, Nicola Gasparini, Pascal Kaienburg, He Yan, Aram Amassian, Christoph Josef Brabec, James Robert Durrant, Iain A. McCulloch

📖 Energy & Environmental Science 📅 2016-01-01 🔗 DOI: 10.1039/c6ee02598f

📄 Abstract

is shown to be associated with the achievement of remarkably low non-geminate and non-radiative recombination losses in these devices. Suppression of non-radiative recombination implies high external electroluminescence quantum efficiencies which are orders of magnitude higher than those of equivalent devices employing fullerene acceptors. Using the balance between reduced recombination losses and good photocurrent generation efficiencies achieved experimentally as a baseline for simulations of the efficiency potential of organic solar cells, we estimate that efficiencies of up to 20% are achievable if band gaps and fill factors are further optimized.

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