SCHOLARLY PUBLICATION

Reversible Alteration of CO 2 Adsorption upon Photochemical or Thermal Treatment in a Metal–Organic Framework

Jinhee Park, Daqiang Yuan, Khanh T. Pham, Jian‐Rong Li, Andrey Andreevich Yakovenko, Hong-Cai “Joe” Zhou

📖 Journal of the American Chemical Society → 📅 2011-12-13 🔗 DOI: 10.1021/ja209197f

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📄 Abstract

A metal-organic framework (MOF) for reversible alteration of guest molecule adsorption, here carbon dioxide, upon photochemical or thermal treatment has been discovered. An azobenzene functional group, which can switch its conformation upon light irradiation or heat treatment, has been introduced to the organic linker of a MOF. The resulting MOF adsorbs different amount of CO(2) after UV or heat treatment. This remarkable stimuli-responsive adsorption effect has been demonstrated through experiments.

📄 Abstract

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