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Ultrathin Spinel LiMn2O4 Nanowires as High Power Cathode Materials for Li-Ion Batteries

Hyun‐Wook Lee, Pandurangan Muralidharan, Riccardo Ruffο, Claudio Maria Mari, Yi Ping Cui, Do Kyung Kim

📄 Abstract

Ultrathin LiMn(2)O(4) nanowires with cubic spinel structure were synthesized by using a solvothermal reaction to produce α-MnO(2) nanowire followed by solid-state lithiation. LiMn(2)O(4) nanowires have diameters less than 10 nm and lengths of several micrometers. Galvanostatic battery testing showed that LiMn(2)O(4) nanowires deliver 100 and 78 mAh/g at very high rate (60C and 150C, respectively) in a larger potential window with very good capacity retention and outstanding structural stability. Such performances are due to both the favorable morphology and the high crystallinity of nanowires.

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